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My workplace recommends S/MIME for secure encrypted emails. My experience so far: not as straightforward as PGP; only works in IE.
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Maybe it's just the Microsoft IE and Outlook skewed flavour of S/MIME that ICT's (insecure) site generates.
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Update: S/MIME certificates now working in Thunderbird (and Outlook, I guess) for digital signatures. But not for encryption :(